Extraction-Spectrophotometric Determination of Osmium Using 4-(2-Pyridylazo)resorcinol

Selective extraction spectrophotometric determination

Solvent Extraction Spectrophotometric Determination of Vanadium Using Sodium Salt of 2-Mercapto-Pyridine-N-Oxide as a Reagent

A solvent-extraction spectrophotometric technique is proposed as a new method for determination of trace quantities of vanadium. Sodium salt of 2-mercapto-pyridine-N-oxide (thione) forms a complex with vanadium instantaneously. The purple 1:2 complex is formed of pH 2.3, easily extracted in chloroform and shows strong absorbance at 500 nm. The extracted complex is found to obey Beer's law i...

Sequential separation and spectrophotometric determination of osmium and platinum with 5-chloro-2-hydroxythiobenzhydrazide.

Osmium was determined spectrophotometrically after coprecipitation with 5-chloro-2-hydroxythiobenzhydrazide at room temperature in the pH range 2.5-5.0 and collection on microcrystalline naphthalene. Beer's law was obeyed in the concentration range 1.8-14.4 ppm of osmium in a chloroform solution at 510 nm. The molar absorptivity and Sandell sensitivity were 1.056 x 10(4) l mol(-1) cm(-1) and 0....

Spectrophotometric Determination of 4-Hydroxy-2-mercapto-6-methylpyrimidine Based on Aggregation of Colloidal Gold Nanoparticles

We report herein the development of a highly sensitive colorimetric method for the detection of 4-hydroxy-2-mercapto-6-methylpyrimidine (MTU) which acts as an anti-thyroid drug utilizing citrate capped gold nanoparticles (Au-NPs). This thiol-containing molecule exhibits intriguing affinity with Au-NPs. The reactivity involves the displacement of the citrate shell by the thiolate shell followed ...

Spectrophotometric determination of molybdenum using surfactant-mediated liquid–liquid extraction

A new spectrophotometric method has been developed for determination of molybdenum using surfactantmediated liquid–liquid extraction. Molybdenum(V) obtained by ascorbic acid reduction in 2.5 M H2SO4 reacted spontaneously with thiocyanate and cetyl trimethyl ammonium bromide (CTAB), forming an intense orange yellow complex that was extracted quantitatively into 1,2-dichloroethane and absorbed at...